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pro vyhledávání: '"Antonella Gervasini"'
Autor:
Secondo Martinengo, Luciano Zanderighi, Tiziana Beringhelli, D. Strumolo, Antonella Gervasini, Franca Morazzoni
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 80:1479
The pyrolysis of γ-Al2O3- and ZrO2-supported [Co4(CO)12] and [Rh4(CO)12] gives highly dispersed metal systems whose electronic properties have been studied by e.s.r. spectroscopy. Paramagnetic formal RhII species (g∥= 2.21, g⊥= 2.11) were observ
Autor:
Giorgio Strukul, Luciano Zanderighi, Franca Morazzoni, D. Strumolo, Francesco Pinna, Antonella Gervasini
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 82:1795
Paramagnetic metal and oxygen species observed when alumina-(or zirconia-supported rhodium, Rh/γ-Al2O3(ZrO2), is obtained by the decarbonylation of [Rh4(CO)12]-Al2O3(ZrO2) are discussed as a function of the decarbonylation temperature (250–600 °C