Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Toshiaki Morimoto"'
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :883
The introduction of a primary aminomethyl unit at the α-position of esters can be achieved in high yield by the silyl trifluoromethanesulphonate-catalysed reaction of ketene silyl acetals (2) with N,N-bis(trimethylsilyl)methoxymethylamine (1).
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1584
A convenient general method for the preparation of sulphenimines by the reaction of aldehydes and ketones with N,N-bis(trimethylsily)sulphenamides in the presence of tretrabutylammonium fluoride catalyst is described.
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1055
N-Silyl-protected primary aminomethyl sulphides and aminomethylphosphonates can be synthesised by the Lewis acid-catalysed reactions of silyl sulphides and silyl phosphites with N,N-bis(trimethylsilyl)methoxymethylamine.
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :794
The introduction of the primary aminomethyl unit at carbon through N,N-bis(trimethylsily)aminomethylation of Grignard and organolithium compounds can be achieved in good yield using N,N-bis(trimethylsily)methoxymethylamine (1).