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Publikováno v:
Journal of the American Chemical Society. 123(11)
Xanthine oxidase is a molybdenum-containing enzyme that catalyzes the hydroxylation of xanthine and a wide variety of other aromatic heterocycles. In the course of the reaction with xanthine and substrates such as 2-hydroxy-6-methylpurine (HMP), the
Publikováno v:
Journal of the American Chemical Society. 131:11606-11614
The photochemical decarbonylation of diphenylcyclopropenone (DPCP) to diphenylacetylene (DPA) proceeds with remarkable efficiency both in solution and in the crystalline solid state. It had been previously shown that excitation to the second electron
Autor:
Donald J. Burton, Haridasan K. Nair
Publikováno v:
Journal of the American Chemical Society. 119:9137-9143
Under UV irradiation (254 nm) at ambient temperature, a degassed mixture of (EtO)2POP(OEt)2 and RfI {Rf = CF3, C2F5, C4F9, C6F13, (CF3)2CF, CF2CFCF2, ClCF2CF2, BrCF2CF2, C6F5, ClCF2CFClCF2CF2, I(CF2)3, I(CF2)4, FO2S(CF2)4, FO2S(CF2)2O(CF2)2} affords
Publikováno v:
Journal of the American Chemical Society. 134(37)
The reaction of CpCr(CO)(3)H with activated alkynes in benzene has been examined. The kinetics of these reactions have been studied with various alkynes, along with the stereochemistry with which the alkynes are hydrogenated. The hydrogenation of phe
Publikováno v:
Journal of the American Chemical Society. 128:15562-15563
Intermolecular arene C-H activation mediated by a divalent nickel species under extremely mild conditions is described. The reactions of either Ni(COD)2 with H[N(o-C6H4PR2)2] (H[R-PNP]; R = iPr, Cy) in benzene at room temperature or [R-PNP]NiCl with