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Autor:
Shanmugam M; Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA., Doan PE, Lees NS, Stubbe J, Hoffman BM
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2009 Mar 11; Vol. 131 (9), pp. 3370-6.
Publikováno v:
Journal of the American Chemical Society. 131(9)
We previously used a combination of CW and pulsed-ENDOR protocols to identify the types of protonated oxygen (OHx) species and their disposition within the FeIII/FeIV cluster of Intermediate X, the direct precursor of the essential diferric-tyrosyl r