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Publikováno v:
Journal of the American Chemical Society. 131(9)
We previously used a combination of CW and pulsed-ENDOR protocols to identify the types of protonated oxygen (OHx) species and their disposition within the FeIII/FeIV cluster of Intermediate X, the direct precursor of the essential diferric-tyrosyl r
Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition
Publikováno v:
Journal of the American Chemical Society. 127:14592-14593
Gas-phase Au atoms deposited onto a multilayer film of molecular oxygen produce atomic oxygen bound to gold clusters. After removal of molecular O2, temperature programmed desorption and molecular beam techniques show that the atomic oxygen readily r