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Publikováno v:
Journal of the American Chemical Society. 120:6661-6672
The steric course of the first step of Pd(0)-catalyzed allylic substitution with stabilized C-nucleophiles can be completely reversed by a suitably positioned coordinating Ph2P group, resulting in an overall inversion (1 → 4 → 5), as opposed to t
Publikováno v:
Journal of the American Chemical Society. 128:15562-15563
Intermolecular arene C-H activation mediated by a divalent nickel species under extremely mild conditions is described. The reactions of either Ni(COD)2 with H[N(o-C6H4PR2)2] (H[R-PNP]; R = iPr, Cy) in benzene at room temperature or [R-PNP]NiCl with
Publikováno v:
Journal of the American Chemical Society. 104:2539-2543
Described is the surface coordination chemistry of cyclohexane, 1,3- and 1,4-cyclohexadiene, and cyclohexene on the low Miller index planes and a stepped surface of nickel and on the platinum (111) and stepped 6(111)X(111) surfaces as established by