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Autor:
Shanahan JP; Department of Chemistry, University of Michigan, 930 N. University, Ann Arbor, Michigan 48109, United States., Mullis DM; Department of Chemistry, University of Michigan, 930 N. University, Ann Arbor, Michigan 48109, United States., Zeller M; H. C. Brown Laboratory, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States., Szymczak NK; Department of Chemistry, University of Michigan, 930 N. University, Ann Arbor, Michigan 48109, United States.
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2020 May 13; Vol. 142 (19), pp. 8809-8817. Date of Electronic Publication: 2020 Apr 30.
Autor:
Olivares AM; University of Rochester , Rochester, New York 14627-0216, United States., Weix DJ; University of Rochester , Rochester, New York 14627-0216, United States.; University of Wisconsin-Madison , Madison, Wisconsin 53706, United States.
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2018 Feb 21; Vol. 140 (7), pp. 2446-2449. Date of Electronic Publication: 2018 Feb 08.
Publikováno v:
Journal of the American Chemical Society. 120:6661-6672
The steric course of the first step of Pd(0)-catalyzed allylic substitution with stabilized C-nucleophiles can be completely reversed by a suitably positioned coordinating Ph2P group, resulting in an overall inversion (1 → 4 → 5), as opposed to t