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pro vyhledávání: '"35"'
Autor:
Frederick G. Bordwell, J.-P. Cheng
Publikováno v:
Journal of the American Chemical Society. 113:1736-1743
Oxidation potentials for 35 phenoxide ions and 3 naphthoxide ions have been combined with their pK HA values to estimated homolytic bond dissociation energies (BDEs) for the O-H bonds in phenols. Comparison with literature values shows that there is
Autor:
Johannes A. M. Hepperle, Brooks J. Culotta, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Jeffrey L. Petersen, Roland Fröhlich, Armido Studer, Timothy H. Warren, Gerald Kehr, Constantin G. Daniliuc, Annika Stute, Birgitta Schirmer, Muhammad Sajid
Publikováno v:
Journal of the American Chemical Society
The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes(2)P-C(6)H(10)-B(C(6)F(5))(2)] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b formed by P/B addition to the nitrogen atom of NO. This species was full
Publikováno v:
Journal of the American Chemical Society. 118:9831-9840
Photostimulated additions of tert-butylmercury halides to 1,6-dienes and enynes, including (CH2CHCH2)2X with X = CH2, C(COEt)2, O, or NCH2CHCH2, form the primary alkylmercury halides resulting from 5-exo-cyclizations of the adduct radicals, t-BuCH2CH