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pro vyhledávání: '"35"'
Autor:
Anne K. Hickey, Daniel J. Mindiola, Jennifer Scott, Maren Pink, Marco G. Crestani, Hongjun Fan, Benjamin F. Wicker
Publikováno v:
Journal of the American Chemical Society. 134(49)
The anilide-methyl complex (PNP)Sc(NH[DIPP])(CH(3)) (1) [PNP(-) = bis(2-diisopropylphosphino-4-tolyl)amide, DIPP = 2,6-diisopropylphenyl] eliminates methane (k(avg) = 5.13 × 10(-4) M(-1) s(-1) at 50 °C) in the presence of pyridine to generate the t
Publikováno v:
Journal of the American Chemical Society. 130:15185-15192
A general method for copper-catalyzed arylation of sp (2) C-H bonds with p K a's below 35 has been developed. The method employs aryl halide as the coupling partner, lithium alkoxide or K 3PO 4 base, and DMF, DMPU, or mixed DMF/xylenes solvent. A var
Publikováno v:
Journal of the American Chemical Society. 119:3619-3620
The autofluorescent age pigments (lipofuscin) which accumulate in the human retinal pigment epithelium (RPE) cells with age are considered to be responsible for causing various eye diseases including age-related macular degeneration (AMD), the leadin