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pro vyhledávání: '"35"'
Autor:
Megan E. Fieser, Joseph W. Ziller, Filipp Furche, Matthew R. MacDonald, Jefferson E. Bates, William J. Evans
Publikováno v:
Journal of the American Chemical Society. 134:8420-8423
The first molecular complexes of holmium and erbium in the +2 oxidation state have been generated by reducing Cp'(3)Ln [Cp' = C(5)H(4)SiMe(3); Ln = Ho (1), Er (2)] with KC(8) in the presence of 18-crown-6 in Et(2)O at -35 °C under argon. Purificatio
Publikováno v:
Journal of the American Chemical Society. 140(44)
Liquid fluoride thorium reactors have been considered as replacements for uranium-based nuclear reactors, having many economic and environmental advantages. The production of thorium is usually accompanied by the separation of thorium from rare earth
Publikováno v:
Journal of the American Chemical Society. 133:15886-15889
An entirely new type of chalcogenide cluster and a new structural mechanism for the formation of large semiconducting tetrahedral clusters have been revealed as a result of crystallization of a templated indium sulfide consisting of an unprecedented
Autor:
Mu-Hyun Baik, Xiaofan Yang
Publikováno v:
Journal of the American Chemical Society. 126(41)
High-level DFT calculations indicate that the singlet ground state of the water-oxidizing blue Ru dimer [(bpy)2(OH2)RuIIIORuIII(OH2)(bpy)2]4+ is not due to a strong coupling of the excess electrons from each of the low-spin d5 RuIII centers across th