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pro vyhledávání: '"35"'
Autor:
Yehuda Zeiri, Barak Hirshberg, Ronnie Kosloff, Naomi Rom, David Furman, William A. Goddard, Faina Dubnikova, Sergey V. Zybin
Publikováno v:
Journal of the American Chemical Society. 136:4192-4200
Activation energy for the decomposition of explosives is a crucial parameter of performance. The dramatic suppression of activation energy in condensed phase decomposition of nitroaromatic explosives has been an unresolved issue for over a decade. We
Publikováno v:
Journal of the American Chemical Society
Ribonucleotide reductases (RNRs) catalyze the conversion of nucleotides to deoxynucleotides in all organisms. Active E. coli class Ia RNR is an α2β2 complex that undergoes reversible, long-range proton-coupled electron transfer (PCET) over a pathwa
Autor:
Jerome A. Berson, Helen S. M. Lu
Publikováno v:
Journal of the American Chemical Society. 119:1428-1438
Methods are described for the synthesis of bis-diazene precursors of catenated tetraradicals. Photodeazetation in a low-temperature matrix of the N-tosylpyrrole member of the series (13) gives mainly the monodeazetated biradical 34, which is characte
Publikováno v:
Journal of the American Chemical Society. 131:2762-2763
The thermodynamic properties of structurally similar Mn(III) and Mn(IV) complexes have been reinvestigated to understand their reactivity with substrates having C-H bonds. The complexes have the general formula [MnH(3)buea(O)](n-), where [H(3)buea](3
Autor:
Yi Lu, Juewen Liu
Publikováno v:
Journal of the American Chemical Society. 129:9838-9839
Copper is a key metal ion both in environment monitoring and in biology, and exposure to high concentration of copper can cause adverse health effects. Although significant progresses have been made in designing fluorescent sensors for diamagnetic me