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Publikováno v:
Journal of the American Chemical Society. 123(32)
When water is heated and pressurized above the critical point, it becomes a suitable solvent to employ organic capping ligands to control and stabilize the synthesis of nanocrystals. Without alkanethiol ligands, Cu(NO(3))(2) hydrolyzes to form polydi
Autor:
Larry R. Faulkner, Pawel J. Kulesza
Publikováno v:
Journal of the American Chemical Society. 110:4905-4913
Cycling the potential between 0.8 and {minus}0.4 V vs. SCE in the colloidal mixture of WO{sub 3}{center dot}2H{sub 2}O/WO{sub 3}{center dot}H{sub 2}O existing in 2 M H{sub 2}SO{sub 4} at 35{degree}C causes the electrodeposition of stable, mixed-valen
Autor:
R.L. Heppolette, R.E. Robertson
Publikováno v:
Journal of the American Chemical Society. 83:1834-1838
Rate data for the hydrolysis of isopropyl bromide in deuterium oxide are determined over a temperature of 35 to 80 deg . By comparison with earlier data for hydrolysis in water, it was shown that the solvent isotope effect (k/sub D// sub 2//sub O// k