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Publikováno v:
Journal of the American Chemical Society. 122:182-183
Methyl-coenzyme M reductase (MCR) catalyzes the chemical step of methane formation by methanogenic organisms. The reaction involves the two-electron reduction of CH{sub 3}S-CoM by N-7-mercaptoheptanoylthreoinine phosphate (CoB-SH). The authors have e
Publikováno v:
Journal of the American Chemical Society. 104:2539-2543
Described is the surface coordination chemistry of cyclohexane, 1,3- and 1,4-cyclohexadiene, and cyclohexene on the low Miller index planes and a stepped surface of nickel and on the platinum (111) and stepped 6(111)X(111) surfaces as established by
Autor:
Burch B. Stewart, Hilton A. Smith
Publikováno v:
Journal of the American Chemical Society. 82:3898-3900
Deuterium gas exchanges slowly with liquid methanol over Raney nickel catalyst at 35 deg . The reaction is zero order with respect to deuterium pressure and has a low activation energy. The influences of catalyst weight, catalyst treatment, and of th