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Publikováno v:
Journal of the American Chemical Society. 128(18)
The silyl-substituted titanocene complex, (eta5-C5Me4SiMe2Ph)2Ti, coordinates dinitrogen upon cooling to -35 degrees C to yield an unprecedented example of a mono(dinitrogen) complex of a substituted bis(cyclopentadienyl) titanium compound, (eta5-C5M
Autor:
Larry R. Faulkner, Pawel J. Kulesza
Publikováno v:
Journal of the American Chemical Society. 110:4905-4913
Cycling the potential between 0.8 and {minus}0.4 V vs. SCE in the colloidal mixture of WO{sub 3}{center dot}2H{sub 2}O/WO{sub 3}{center dot}H{sub 2}O existing in 2 M H{sub 2}SO{sub 4} at 35{degree}C causes the electrodeposition of stable, mixed-valen
Autor:
Lester Andrews, Sefik Suezer
Publikováno v:
Journal of the American Chemical Society. 109:300-304
One-to-one complexes between Li, Na, K, and Cs atoms and NH/sub 3/ have been studied by using matrix IR spectroscopy. New bands at 1133, 1079, 1064, and 1049 cm/sup -1/ are assigned to perturbed nu/sub 2/ modes, and bands at 3277, 3294, 3292, and 328