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Publikováno v:
Journal of the American Chemical Society. 114:1743-1749
pH-rate profiles, primary kinetic isotope effects, deuterium substitution patterns, and pH-product ratios in the presence of added nucleophiles provide evidence for the following overlapping set of mechanisms for the hydrolysis of methanesulfonyl chl
Autor:
James P. Ferris, Kunio Kawamura
Publikováno v:
Journal of the American Chemical Society. 116(17)
The rate constants for the condensation reaction of the 5'-phosphorimidazolide of adenosine (ImpA) to form dinucleotides and oligonucleotides have been measured in the presence of Na(+)-volclay (a Na(+)-montmorillonite) in pH 8 aqueous solution at 25