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Publikováno v:
Journal of the American Chemical Society. 132:13902-13913
Structures of K(2)(H(2)O)(2)B(12)F(12) and K(2)(H(2)O)(4)B(12)F(12) were determined by X-ray diffraction. They contain [K(μ-H(2)O)(2)K](2+) and [(H(2)O)K(μ-H(2)O)(2)K(H(2)O)](2+) dimers, respectively, which interact with superweak B(12)F(12)(2-) an
Autor:
Koichiro Ishimori, Isao Morishima, Takehiko Tosha, Shiro Yoshioka, Hiroshi Hori, Satoshi Takahashi
Publikováno v:
Journal of the American Chemical Society. 124:14571-14579
Structural and functional roles of the hydrogen bonding network that surrounds the heme-thiolate coordination of P450(cam) from Pseudomonas putida were investigated. A hydrogen bond between the side chain amide of Gln360 and the carbonyl oxygen of th
Publikováno v:
Journal of the American Chemical Society. 130:2428-2429
Hydrogen bonds play critical roles in protein structure, stability, and function. Conventionally, hydrogen bonds are mainly determined by X-ray crystallography and NOE-based NMR spectroscopy in indirect manners. In recent years, it was demonstrated t