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Publikováno v:
Journal of the American Chemical Society. 132:10021-10023
The preparation of tantalaziridine-hydride complex (Ar[(t)BuCH(2)]N)(2)(eta(2)-(t)Bu(H)CNAr)TaH (1) is reported (Ar = 3,5-Me(2)C(6)H(3)). While stable for months in the solid state at -35 degrees C, in solution this complex undergoes partial conversi
Autor:
Curtis E. Johnson, Richard Eisenberg
Publikováno v:
Journal of the American Chemical Society. 107:3148-3160
The oxidative addition of H2 to the iridium(I) chelates IrX(CO) (dppe) (X(-) = Cl(-), Br(-), I(-), Cn(-), H(-), PPh3; dppe = 1, 2-bis-(diphenylphosphino)ethane) proceeds with > 99% steroselectivity to yield a cis dihydride product with one hydride tr
Autor:
D. B. Jacobson, Ben S. Freiser
Publikováno v:
Journal of the American Chemical Society. 106:3891-3899
The gas-phase reactions of FeCH/sub 3//sup +/ and CoCH/sub 3//sup +/ with aliphatic alkanes up to C/sub 6/H3exclamation/sub 4/ were studied. FeCH/sub 3//sup +/ is completely unreactive with the aliphatic alkanes, while CoCH/sub 3//sup +/ reacts with