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Publikováno v:
Journal of the American Chemical Society. 105:7337-7345
Studies have been conducted on the ground-state and excited-state solvolyses of the isomeric 7,8-dichloro derivatives of benzonaphthobicyclo(2.2.2)octadiene and benzoveratrobicyclo(2.2.2)octadiene. The silver ion assisted ground-state reactions proce
Publikováno v:
Journal of the American Chemical Society. 131:11606-11614
The photochemical decarbonylation of diphenylcyclopropenone (DPCP) to diphenylacetylene (DPA) proceeds with remarkable efficiency both in solution and in the crystalline solid state. It had been previously shown that excitation to the second electron
Publikováno v:
Journal of the American Chemical Society. 114:2277-2279
The recent isolation of fullerenes such as C{sub 60} and C{sub 70} has led to several studies of the reactivity and physical properties of their excited states. The authors recently reported that triplet C{sub 60} ({sup 3}C{sub 60}) is formed with a
Publikováno v:
Journal of the American Chemical Society. 111:8947-8948
The search for organometallic complexes that emit in fluid solution at room temperature has been intensely pursued for the past 35 years because of the importance of an understanding of excited-state properties to the areas of solar energy conversion