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Autor:
Shanmugam, Muralidharan1, Doan, Peter E.1, Lees, Nicholas S.1, Stubbe, JoAnne2 stubbe@MlT.EDU, Hoffman, Brian M.1 bmh@northwestern.edu
Publikováno v:
Journal of the American Chemical Society. 3/11/2009, Vol. 131 Issue 9, p3370-3376. 7p. 4 Diagrams, 1 Chart, 2 Graphs.
Publikováno v:
Journal of the American Chemical Society. 131(9)
We previously used a combination of CW and pulsed-ENDOR protocols to identify the types of protonated oxygen (OHx) species and their disposition within the FeIII/FeIV cluster of Intermediate X, the direct precursor of the essential diferric-tyrosyl r