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Autor:
Johannes A. M. Hepperle, Brooks J. Culotta, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Jeffrey L. Petersen, Roland Fröhlich, Armido Studer, Timothy H. Warren, Gerald Kehr, Constantin G. Daniliuc, Annika Stute, Birgitta Schirmer, Muhammad Sajid
Publikováno v:
Journal of the American Chemical Society
The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes(2)P-C(6)H(10)-B(C(6)F(5))(2)] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b formed by P/B addition to the nitrogen atom of NO. This species was full
Autor:
Robert J. Doedens, Filipp Furche, Joseph W. Ziller, David S. Lee, William J. Evans, Ming Fang, Jefferson E. Bates
Publikováno v:
Journal of the American Chemical Society. 133:3784-3787
Examination of the Y[N(SiMe(3))(2)](3)/KC(8) reduction system that allowed isolation of the (N(2))(3-) radical has led to the first evidence of Y(2+) in solution. The deep-blue solutions obtained from Y[N(SiMe(3))(2)](3) and KC(8) in THF at -35 °C u