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Autor:
Clive Yik-Sham Chung, Pei Liu, Kevin J. Bruemmer, Evan W. Miller, Christopher J. Chang, Kaoru Saijo, Yuki Nishikawa, Sumin Lee, Itaru Hamachi, Laura Craciun
Publikováno v:
Journal of the American Chemical Society, vol 142, iss 35
J Am Chem Soc
J Am Chem Soc
Copper is a required nutrient for life and particularly important to the brain and central nervous system. Indeed, copper redox activity is essential to maintaining normal physiological responses spanning neural signaling to metabolism, but at the sa
Autor:
Somdatta Ghosh, Abhishek Dey, Charles P. Scholes, Vladimir M. Grigoryants, Edward I. Solomon, Oleg M. Usov, Yan Sun
Publikováno v:
Journal of the American Chemical Society. 129(34)
Copper nitrite reductase (NiR) is a homotrimeric enzyme, containing a T1 copper site, which transfers electrons to the T2 catalytic site, where nitrite is reduced by one electron to nitric oxide (NO2− + 2H+ + e− → NO + H2O).1–3 Recently a sid