Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Martin Albrecht"'
Autor:
Gema Rodríguez, Jeroen Schoenmaker, Alan Ford, Martin Lutz, Gerard van Koten, Anthony L. Spek, Martin Albrecht
Publikováno v:
Journal of the American Chemical Society. 124:5127-5138
The reactivity of the bifunctionalized ligand NC(Br)N-I 1 [IC(6)H(2)(CH(2)NMe(2))(2)-3,5-Br-4] has been studied as a versatile synthon for organic and/or organometallic synthesis. Chemoselective metalation (M = Pd, Pt, Li) at the C(aryl)-I or C(aryl)
Publikováno v:
Journal of the American Chemical Society. 130(44)
Supramolecular principles have been applied for improving the spin crossover activity of metal centers due to cooperative effects in solution. Thus, incorporation of alkyloxy tails at the phenyl group of Fe(sal₂trien) 2a provides amphiphilic comple
Publikováno v:
Journal of the American Chemical Society. 130(41)
The [3 + 2] cycloaddition of azides and acetylenes followed by nitrogen quaternization was applied for the generation of novel and highly modular triazolium salts. The selective substitution of the 1,3,4-substitution pattern presets such salts as pre
Publikováno v:
Journal of the American Chemical Society. 124(35)
We show that imidazolium salts do not always give normal or even aromatic carbenes on metalation, and the chemistry of these ligands can be much more complicated than previously thought. N,N'-disubstituted imidazolium salts of type [(2-py)(CH(2))(n)(
Publikováno v:
Journal of the American Chemical Society. 123(30)
The reaction of cationic platinum aqua complexes 2 [Pt(C(6)H(2)[CH(2)NMe(2)](2)-E-4)(OH(2))](X') (X' = SO(3)CF(3), BF(4)) with alkyl halides RX gave various air-stable arenium complexes 3-5 containing a new C-C bond (R = Me, 3; Et, 4; Bn, 5). Electro