Zobrazeno 1 - 10
of 59
pro vyhledávání: '"35"'
Publikováno v:
Journal of the American Chemical Society. 115:11616-11617
Autor:
Morton Raban, Gaku Yamamoto
Publikováno v:
Journal of the American Chemical Society. 101:5890-5895
Publikováno v:
Journal of the American Chemical Society
The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal-organic frameworks, MOF-519
Autor:
Megan E. Fieser, Joseph W. Ziller, Filipp Furche, Matthew R. MacDonald, Jefferson E. Bates, William J. Evans
Publikováno v:
Journal of the American Chemical Society. 134:8420-8423
The first molecular complexes of holmium and erbium in the +2 oxidation state have been generated by reducing Cp'(3)Ln [Cp' = C(5)H(4)SiMe(3); Ln = Ho (1), Er (2)] with KC(8) in the presence of 18-crown-6 in Et(2)O at -35 °C under argon. Purificatio
Autor:
Hiroyasu Furukawa, Omar M. Yaghi
Publikováno v:
Journal of the American Chemical Society. 131:8875-8883
Dihydrogen, methane, and carbon dioxide isotherm measurements were performed at 1-85 bar and 77-298 K on the evacuated forms of seven porous covalent organic frameworks (COFs). The uptake behavior and capacity of the COFs is best described by classif
Publikováno v:
Journal of the American Chemical Society. 143:7306-7313
A Co-catalyzed highly regio- and enantioselective reductive coupling of alkynes and aldehydes has been developed under visible light photoredox dual catalysis. A variety of enantioenriched allylic alcohols have been obtained by using unsymmetrical in
Autor:
John C. Linehan, and Thomas E. Bitterwolf, J. Timothy Bays, Clement R. Yonker, Scott L. Wallen
Publikováno v:
Journal of the American Chemical Society. 119:10170-10177
The in situ photolytic exchange of ethylene and hydrogen for carbon monoxide on cymantrene (CpMn(CO)3 , Cp = η5-cyclopentadienyl) and methylcymantrene (MeCpMn(CO)3, MeCp = monomethyl-η5-cyclopentadienyl) dissolved in subcritical and supercritical s
Autor:
Anne K. Hickey, Daniel J. Mindiola, Jennifer Scott, Maren Pink, Marco G. Crestani, Hongjun Fan, Benjamin F. Wicker
Publikováno v:
Journal of the American Chemical Society. 134(49)
The anilide-methyl complex (PNP)Sc(NH[DIPP])(CH(3)) (1) [PNP(-) = bis(2-diisopropylphosphino-4-tolyl)amide, DIPP = 2,6-diisopropylphenyl] eliminates methane (k(avg) = 5.13 × 10(-4) M(-1) s(-1) at 50 °C) in the presence of pyridine to generate the t
Publikováno v:
Journal of the American Chemical Society. 115:11906-11917
The MM3 force field has been extended to cover aromatic heterocycles of the pyridine and pyrrole types. Structures (32 compounds), heats of formation (35 compounds), dipole moments (35 compounds), and vibrational spectra (11 compounds) have been exam
Autor:
Benjamin W. Rawe, Kerim Samedov, Azalea Uva, Derek P. Gates, Zeyu Han, Harvey K. MacKenzie, Henry T G Walsgrove
Publikováno v:
Journal of the American Chemical Society. 142:10319-10324
A polymeric phosphine sensor is reported that exhibits bright blue fluorescence in the presence of gold(I/III) ions but is nonemissive with other metal ions. Specifically, solutions of a poly(p-arylenediethynylene phosphine) copolymer are 35 or 94 ti