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pro vyhledávání: '"35"'
Publikováno v:
Journal of the American Chemical Society. 112:8182-8183
The authors are investigating the synthesis and sorption properties of a new class of open framework solids with the goal of being able to carry out shape-selective and size exclusionary chemical reactions within the pores of a microporous solid. If
Autor:
Jordi Benet-Buchholz, Teodor Parella, T. Daniel P. Stack, Xavi Ribas, Albert Poater, Alicia Casitas, Carlos Calle, Antoni Llobet, Raül Xifra, A. Schweiger, Miquel Solà, George Mitrikas, Laura Gómez
Publikováno v:
© Journal of the American Chemical Society, 2010, vol. 132, núm. 35, p. 12299-12306
Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
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Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
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The present study provides mechanistic details of a mild aromatic C-H activation effected by a copper(II) center ligated in a triazamacrocylic ligand, affording equimolar amounts of a CuIII-aryl species and CuIspecies as reaction products. At low tem
Publikováno v:
Journal of the American Chemical Society. 105:6318-6320
The reduction has been effected by using a variety of Pd (palladium)-based catalysts. The typical procedure was to suspend 0.25 g of catalyst in 25 cc of an aqueous solution of sodium bicarbonate purged slowly with hydrogen gas. The sodium formate co
Publikováno v:
Journal of the American Chemical Society. 110:7868-7870
The reactivity of Os{sub 2}(CO){sub 8}({mu}-CH{sub 2}) and other diosmacyclopropanes toward CO has been investigated. The preparation of Os{sub 2}(CO){sub 8}({mu}-CHCH{sub 3}) from ethylene ditriflate is described, and the reversible carbonylation of
Autor:
Burch B. Stewart, Hilton A. Smith
Publikováno v:
Journal of the American Chemical Society. 82:3898-3900
Deuterium gas exchanges slowly with liquid methanol over Raney nickel catalyst at 35 deg . The reaction is zero order with respect to deuterium pressure and has a low activation energy. The influences of catalyst weight, catalyst treatment, and of th