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Autor:
Frederick G. Bordwell, J.-P. Cheng
Publikováno v:
Journal of the American Chemical Society. 113:1736-1743
Oxidation potentials for 35 phenoxide ions and 3 naphthoxide ions have been combined with their pK HA values to estimated homolytic bond dissociation energies (BDEs) for the O-H bonds in phenols. Comparison with literature values shows that there is
Publikováno v:
Journal of the American Chemical Society. 131:2762-2763
The thermodynamic properties of structurally similar Mn(III) and Mn(IV) complexes have been reinvestigated to understand their reactivity with substrates having C-H bonds. The complexes have the general formula [MnH(3)buea(O)](n-), where [H(3)buea](3