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pro vyhledávání: '"35"'
Autor:
Johannes A. M. Hepperle, Brooks J. Culotta, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Jeffrey L. Petersen, Roland Fröhlich, Armido Studer, Timothy H. Warren, Gerald Kehr, Constantin G. Daniliuc, Annika Stute, Birgitta Schirmer, Muhammad Sajid
Publikováno v:
Journal of the American Chemical Society
The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes(2)P-C(6)H(10)-B(C(6)F(5))(2)] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b formed by P/B addition to the nitrogen atom of NO. This species was full
Autor:
Jordi Benet-Buchholz, Teodor Parella, T. Daniel P. Stack, Xavi Ribas, Albert Poater, Alicia Casitas, Carlos Calle, Antoni Llobet, Raül Xifra, A. Schweiger, Miquel Solà, George Mitrikas, Laura Gómez
Publikováno v:
© Journal of the American Chemical Society, 2010, vol. 132, núm. 35, p. 12299-12306
Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
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Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
instname
The present study provides mechanistic details of a mild aromatic C-H activation effected by a copper(II) center ligated in a triazamacrocylic ligand, affording equimolar amounts of a CuIII-aryl species and CuIspecies as reaction products. At low tem
Publikováno v:
Journal of the American Chemical Society. 119:2795-2803
Precursors for the selective generation of C-2 glyceryl radicals were synthesized, and the chemical behavior of the corresponding radicals was investigated by ESR spectroscopy, product analysis, and kinetic measurements. It was found that cleavage of
Autor:
M. David Curtis and, Scott H. Druker
Publikováno v:
Journal of the American Chemical Society. 119:1027-1036
The kinetics of the reaction of a series of aromatic and aliphatic thiols with cluster 1 were determined. These reactions form cluster 2 and the arene or alkane corresponding to the thiol: Cp‘2Mo2Co2S3(CO)4 (1) + RSH → Cp‘2Mo2Co2S4(CO)2 (2) + R