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Highly sensitive and selective gold(I) recognition by a metalloregulator in Ralstonia metallidurans.
Autor:
Jian X; Department of Chemistry, 929 East 57th Street, The University of Chicago, Chicago, Illinois 60637, USA., Wasinger EC, Lockard JV, Chen LX, He C
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2009 Aug 12; Vol. 131 (31), pp. 10869-71.
Publikováno v:
Journal of the American Chemical Society. 131(31)
A MerR family metalloregulatory protein CupR selectively responds to gold stress in Ralstonia metallidurans. A distorted trigonal geometry appears to be used by CupR to achieve the highly sensitive (K(d) approximately 10(-35) M) and selective recogni