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Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition
Publikováno v:
Journal of the American Chemical Society. 127:14592-14593
Gas-phase Au atoms deposited onto a multilayer film of molecular oxygen produce atomic oxygen bound to gold clusters. After removal of molecular O2, temperature programmed desorption and molecular beam techniques show that the atomic oxygen readily r
Publikováno v:
Journal of the American Chemical Society. 97:7054-7068
The cocondensation reactions of Co atoms with CO at 6 to 15$sup 0$K were investigated for the first time using matrix infrared, Raman, uv-visible, and ESR spectroscopy. Using extremely low Co concentrations (Co:M approximately equal to 1:10$sup 4$ to