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Autor:
Larry E. Overman, David W. C. MacMillan, Christopher C. Nawrat, Yuriy Slutskyy, Christopher R. Jamison
Publikováno v:
Journal of the American Chemical Society, vol 137, iss 35
Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient al
Autor:
Armando Lopez, José A. Dobado, José F. Quílez del Moral, M. Mar Herrador, Alejandro F. Barrero, Victoriano Domingo, Horacio R. Dieguez, Jesús F. Arteaga
Publikováno v:
Journal of the American Chemical Society. 132(1)
Investigations detailed herein, including density functional theory (DFT) calculations, demonstrate that the formation of either alkoxy- or hydroxy-Ti(III) complexes considerably decreases the energy of activation for C-O bond homolysis. As a consequ