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pro vyhledávání: '"35"'
Autor:
Benjamin W. Rawe, Kerim Samedov, Azalea Uva, Derek P. Gates, Zeyu Han, Harvey K. MacKenzie, Henry T G Walsgrove
Publikováno v:
Journal of the American Chemical Society. 142:10319-10324
A polymeric phosphine sensor is reported that exhibits bright blue fluorescence in the presence of gold(I/III) ions but is nonemissive with other metal ions. Specifically, solutions of a poly(p-arylenediethynylene phosphine) copolymer are 35 or 94 ti
Autor:
Petra Rudolf, Jochem T. van Herpt, Ben L. Feringa, Sumit Kumar, Regis Y. N. Gengler, Ryan C. Chiechi
Publikováno v:
Journal of the American Chemical Society, 138(38), 12519-12526. AMER CHEMICAL SOC
Journal of the American Chemical Society
Journal of the American Chemical Society
This paper describes the photo-induced switching of conductance in tunneling junctions comprising self-assembled monolayers of a spiropyran moiety using eutectic Ga-In top contacts. Despite separation of the spiropyran unit from the electrode by a lo
Publikováno v:
Journal of the American Chemical Society. 138:2500-2503
The synthesis and isolation of stable main group radicals remains an ongoing challenge. Here we report the application of frustrated Lewis pair chemistry to the synthesis of boron-containing radicals. H2 activation with polyaromatic diones and B(C6F5
Publikováno v:
Journal of the American Chemical Society. 139(25)
The Brønsted acid sites of H-ZSM-5 and ferrierite reversibly adsborb linear pentenes via hydrogen bonding, rapidly isomerizing the double bond. On H-ZSM-5, dimerization of adsorbed pentenes occurs at a slower rate and leads to pentyl ester covalentl
Autor:
Johannes A. M. Hepperle, Brooks J. Culotta, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Jeffrey L. Petersen, Roland Fröhlich, Armido Studer, Timothy H. Warren, Gerald Kehr, Constantin G. Daniliuc, Annika Stute, Birgitta Schirmer, Muhammad Sajid
Publikováno v:
Journal of the American Chemical Society
The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes(2)P-C(6)H(10)-B(C(6)F(5))(2)] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b formed by P/B addition to the nitrogen atom of NO. This species was full
Autor:
Deepak K. Prusty, Andreas Herrmann
Publikováno v:
Journal of the American Chemical Society
Journal of the American Chemical Society, 132(35), 12197-12199. AMER CHEMICAL SOC
Journal of the American Chemical Society, 132(35), 12197-12199. AMER CHEMICAL SOC
Fluorogenic reactions have recently emerged as a powerful tool for detection, diagnostics, and biosensing applications in a chemical and biological context. However, conventional fluorogenic systems reported to date rely on energy- or photoinduced el