Zobrazeno 1 - 7
of 7
pro vyhledávání: '"35"'
Autor:
Harry C. Dorn, Rong Huang, Steven Stevenson, Katelyn R. Tepper, Hannah M. Franklin, Kevin Cover, Xiaoyang Liu, Narasimhamurthy Shanaiah, Ryan M. Koenig, Diego Troya, Xiaoling Wang, D. Mathew Sublett, Xu Feng, Tiffany L. Seeler, Robert J. Bodnar
Publikováno v:
Journal of the American Chemical Society. 143:4593-4599
Although fullerenes were discovered nearly 35 years ago, scientists still struggle to isolate "single molecule" tubular fullerenes larger than C90. In similar fashion, there is a paucity of reports for pristine single-walled carbon nanotubes (SWNTs).
Publikováno v:
Journal of the American Chemical Society. 141:3258-3264
Birefringent materials, the key components in modulating the polarization of light, are of great importance in optical communication and the laser industry. Limited by their transparency range, few birefringent materials can be practically used in th
Publikováno v:
Journal of the American Chemical Society. 140(44)
Liquid fluoride thorium reactors have been considered as replacements for uranium-based nuclear reactors, having many economic and environmental advantages. The production of thorium is usually accompanied by the separation of thorium from rare earth
Publikováno v:
Journal of the American Chemical Society. 138:2500-2503
The synthesis and isolation of stable main group radicals remains an ongoing challenge. Here we report the application of frustrated Lewis pair chemistry to the synthesis of boron-containing radicals. H2 activation with polyaromatic diones and B(C6F5
Autor:
Jeremy M. Smith, Brian M. Hoffman, Martin L. Kirk, Benjamin W. Stein, Deepak Subedi, George E. Cutsail
Publikováno v:
Journal of the American Chemical Society
The recently synthesized and isolated low-coordinate Fe(V) nitride complex has numerous implications as a model for high-oxidation states in biological and industrial systems. The trigonal [PhB((t)BuIm)3Fe(V)≡N](+) (where (PhB((t)BuIm)3(-) = phenyl
Autor:
Johannes A. M. Hepperle, Brooks J. Culotta, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Jeffrey L. Petersen, Roland Fröhlich, Armido Studer, Timothy H. Warren, Gerald Kehr, Constantin G. Daniliuc, Annika Stute, Birgitta Schirmer, Muhammad Sajid
Publikováno v:
Journal of the American Chemical Society
The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes(2)P-C(6)H(10)-B(C(6)F(5))(2)] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b formed by P/B addition to the nitrogen atom of NO. This species was full
Autor:
Gleb Sorohhov, Sara Sangtarash, Silvio Decurtins, Thomas Wandlowski, Hatef Sadeghi, Juerg Hauser, Colin J. Lambert, Wenjing Hong, Cancan Huang, Shi-Xia Liu
Publikováno v:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Sangtarash, Sara; Huang, Cancan; Sadeghi, Hatef; Sorohhov, Gleb; Hauser, Juerg; Wandlowski, Thomas; Hong, Wenjing; Decurtins, Silvio; Liu, Shi-Xia; Lambert, Colin J. (2015). Searching the hearts of graphene-like molecules for simplicity, sensitivity and logic. Journal of the American Chemical Society, 137(35), pp. 11425-11431. American Chemical Society 10.1021/jacs.5b06558
Sangtarash, Sara; Huang, Cancan; Sadeghi, Hatef; Sorohhov, Gleb; Hauser, Juerg; Wandlowski, Thomas; Hong, Wenjing; Decurtins, Silvio; Liu, Shi-Xia; Lambert, Colin J. (2015). Searching the hearts of graphene-like molecules for simplicity, sensitivity and logic. Journal of the American Chemical Society, 137(35), pp. 11425-11431. American Chemical Society 10.1021/jacs.5b06558
If quantum interference patterns in the hearts of polycyclic aromatic hydrocarbons (PAHs) could be isolated and manipulated, then a significant step towards realizing the potential of single-molecule electronics would be achieved. Here we demonstrate