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Publikováno v:
J Am Chem Soc
We report an air-stable diradical dication of chiral D(2)-symmetric conjoined bis[5]diazahelicene with unprecedented high spin (triplet) ground state, singlet triplet energy gap, ΔE(ST) = 0.3 kcal mol(−1). The diradical dication possesses closed-s
Publikováno v:
Journal of the American Chemical Society. 141:3258-3264
Birefringent materials, the key components in modulating the polarization of light, are of great importance in optical communication and the laser industry. Limited by their transparency range, few birefringent materials can be practically used in th
Autor:
Paul A. Dube, Richard T. Oakley, Craig M. Robertson, Stephen M. Winter, Joanne W. L. Wong, Abdeljalil Assoud, Aaron Mailman
Publikováno v:
Journal of the American Chemical Society. 137(3)
The alternating ABABAB π-stacked architecture of the EtCN solvate of the iodo-substituted, oxobenzene-bridged bisdithiazolyl radical IBBO (space group Pnma) gives rise to strong ferromagnetic exchange along the π-stacks, and the material orders as
Autor:
Fiala, R., Spackova, N., Foldynová-Trantírková, S., Sponer, J., Sklenár, V., Trantirek, L., Cellular Protein Chemistry, Sub Cellular Protein Chemistry
Publikováno v:
Journal of the American Chemical Society, 133(35), 13790. American Chemical Society
In this work, a novel NMR method for the identification of preferential coordination sites between physiologically relevant counterions and nucleic acid bases is demonstrated. In this approach, the NMR cross-correlated relaxation rates between the ar