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Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 40:91-96
Ion exchange behaviour of Zr(HPO4)(NaPO4)·5H2O towards HgCl2 solutions has been examined. Na+ and H+ ions were released by the exchanger in a ratio which depended on the pH. Uptake and rate of exchange were relatively high considering that Hg is str
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 37:1073-1077
35Cl and 81Br NMR relaxation time measurements are used to determine the equilibrium positions in reactions of the form RSHgX + Y = RSHgY + X where X is chloride or bromide, and Y is hydroxide ion, histidine, thiosulfate and sulfite. The data require
Autor:
Saroja Raman
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 43:1855-1858
The kinetics of abstraction of CN− from hexacyano ferrate (II) by HgCl2 in the presence of excess 2,2′ bipyridine is reported. The products formed are tetracyano bipyridine-Fe(II) and tris bipyridine-Fe(II) depending on whether Fe(CN)64− or HgC
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 39:395-399
The distribution of vanadium(IV) between hydrochloric acid solutions and organic solutions of tri- n -octylamine or tricaprylmethylammonium chloride has been investigated under different conditions. Both phases have been examined by spectrophometry,
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 43:2659-2664
Tri-p-tolyltin(IV) carboxylate complexes of the type (p-CH3). C6H4)3SnOCOR where R = Methyl, mono-, di- and trichloromethyl, ethyl, n-propyl, n-butyl, n-pentyl or phenyl, have been prepared by the reaction of tri-p-tolyltin chloride with the respecti
Autor:
R.G. Sud, K. C. Malhotra
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 38:393-396
Tetrachlorides of tin, titanium, zirconium, thorium and silicon form compounds of composition SnCl 2 (CH 2 ClCOO) 2 , Ti(CH 2 ClCOO) 4 , Zr(CH 2 ClCOO) 4 , Th(CH 2 ClCOO) 4 and Si 2 O(CH 2 ClCOO) 6 when refluxed with excess of monochloroacetic acid.
Autor:
Lynn A. McDonald, Douglas X. West
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 43:1507-1510
Cu(II) complexes have been prepared with N-isopropyl-2-picolinamine N-oxide (IPA) employing the perchlorate, tetrafluoroborate, nitrate, chloride and bromide salts. Preparative molar ratios of 4:1 and 2:1 ligand to Cu(II) salt yielded the following u
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 38:1183-1186
Zinc 8-hydroxyquinoline complexes are extracted into a chloroform phase as a mixture of two species. Which of the two is extracted predominantly into the chloroform phase depends primarily on the kind of anion in the aqueous phase. The species extrac
Autor:
M.S. Reason, A.G. Massey
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 37:1593-1597
The thermally stable B 9 Br 9 is formed when either boron tribromide or diboron tetrabromide is subjected to a silent electric discharge. The mixed halides B 7 ClBr 6 , B 8 ClBr 7 , B 9 ClBr 8 , B 9 Cl 2 Br 7 , B 9 Cl 3 Br 6 and B 10 ClBr 9 are among
Autor:
Carole J. Barton, T.V. Healy
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 36:2579-2583
The extraction of cuprous chloride by a series of alkyl, aryl and mixed alkyl-aryl tertiary phosphites (S) is described, complexes of the types CuCl . S and CuCl . 2S being formed. The high specificity of these phosphites for copper (I) relative to o