Zobrazeno 1 - 10
of 14
pro vyhledávání: ''
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 41:77-83
Autor:
E.J. Malkiewich, A. Clearfield
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 25:237-240
Co-ordination complexes of zirconium (IV) chloride with a number of amides have been prepared and their infra-red spectra examined. The amides are bonded to the zirconium atom through the carbonyl oxygen. Tertiary amides form diaddition complexes. Wi
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 32:977-986
Stability constants of the chloride and nitrate complexes of neptunium (V) and neptunium (VI) have been determined in HClO 4 of concentrations ranging from 0·3 to 0·8. This was done by measuring the potentials of chemical cells containing equimolar
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 30:2501-2511
The rate of the electron exchange reaction between U(IV) and U(VI) has been studied in high concentrations of hydrochloric acid and was found to be accelerated by large concentrations of chloride ion. From the rates at different temperatures, ranging
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 31:3043-3047
A method is developed for successive separation of some sulphur anions including sulphide, sulphite and thiosulphate by anion exchange chromatography. Potassium chloride proved adequate for their mutual separation. The distribution behaviour of the i
Autor:
Arthur W. Adamson
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 13:275-285
The ion Cr(H 2 O) 6 3+ is found to undergo second order photochemical substitution reactions with thiocyanate and chloride ions, and, likewise, Cr(NH 3 ) 5 (H 2 O) 3+ , with thiocyanate ion. Quantum yields for the forward and reverse reactions are gi
Autor:
T. Moeller, V. Galasyn
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 12:259-265
Solvated rare-earth metal iodides having the general formula LnI3·8DMF (Ln = La, Pr Nd, Sm, or Gd; DMF = N:N′-dimethylformamide) have been prepared by reaction of the hydrated acetate with acetyl iodide in dimethylformamide or by metathesis betwee
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 8:203-208
Preliminary investigations on some reactions of platinum (IV) complexes are reported. Substitution and exchange reactions of platinum (IV) complexes were observed to be accelerated both by light and by platinum (II). Catalysis by Pt (en) 2 2 + of the
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 4:216-219
Anhydrous thorium chloride dissolves vigorously and readily in anhydrous ethylenediamine. The resulting solutions show the conductance behaviour of solutions of weak electrolytes. Electrolysis of such solutions gives cathodic evolution of hydrogen an
Autor:
R.E. Panzer, J.F. Suttle
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 13:244-247
A dark red co-ordination compound ofuranium, 5UCl5·CCl2CClCOCl is reported. The material is the primary reaction product from uranium trioxide and hexachloropropene. It is readily dechlorinated to form uranium tetrachloride, trichloroacrylyl c