Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Eugenia V. Peresypkina"'
Autor:
Vladimir P. Fedin, Cristian Vicent, Maxim N. Sokolov, Pavel A. Abramov, Eugenia V. Peresypkina, A. V. Virovets
Publikováno v:
Journal of Cluster Science. 20:83-92
Reaction of [Mo6(μ3-Cl)8Cl6]2− with H2Se, generated in situ from ZnSe and 4 M HCl under hydrothermal conditions lead to the substitution of one or two bridging chlorides, depending on the reagents ratio. With the Mo6/ZnSe 1:3 molar ratio [Mo6(μ3-
Autor:
Alexander V. Virovets, Pavel A. Abramov, Maxim N. Sokolov, Eugenia V. Peresypkina, Vladimir P. Fedin
Publikováno v:
Journal of Cluster Science. 18:597-605
Reaction of [MoOCl5]2− with in situ generated H2Se under hydrothermal conditions (4M HCl, 140 °C) leads to reduction of Mo(V) to Mo(IV) with the formation of a triangular cluster Mo3(μ3-Se)(μ-O) 3 4+ in high yield. It is present in HCl solutions