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Publikováno v:
Inorganic Chemistry Communications. 85:21-25
Presented are the solvothermal syntheses, structures, characterizations, and luminescent properties of four novel organic-modified cadmium chloride complexes constructed from CdCl2 and imidazole (or its derivatives), namely [CdCl2(Im)4] (1, Im = imid
Publikováno v:
Inorganic Chemistry Communications. 83:92-96
A ditopic 18-membered N2O2S2-macrocycle (L) incorporating hard (NO2) and soft (NS2) binding sites in each side was employed and its three complexes (1–3) exhibiting different stoichiometries, geometries, and topologies have been prepared and struct
Publikováno v:
Inorganic Chemistry Communications. 71:27-31
The reaction of an Eu(III) complex of the protonated form of the macrocyclic Schiff base derived from 1,3-diamino-2-hydroxypropane and 2,6-diformylphenol, [Eu(H4L)Cl3], with three equivalents of base results in a mononuclear complex of the triply dep
Publikováno v:
Inorganic Chemistry Communications. 66:73-78
In the present study, iron complexes modified by differently substituted monodentate pyridine ligands containing a [Fe–O–Fe] unit have been synthesized, isolated and characterized. Noteworthy, the complexes are easily accessible by the reaction o
Publikováno v:
Inorganic Chemistry Communications. 58:67-70
Two new Mn(II) and Co(II) coordination polymers with azide and zwitterionic dicarboxylate ligands L1 and L2 (L1 = [4-((1-carboxylatobenzyl)pyridimium-3-yl) benzoic acid] chloride, L2 = [1,1′-bis(4-carboxylatobenzyl)-4,4′-bipyridinium] dichloride)
Autor:
Rafal Kruszynski, Mohammad Azam, Agata Trzesowska-Kruszynska, Saud I. Al-Resayes, Ambarish Verma, Uttam Pati
Publikováno v:
Inorganic Chemistry Communications. 46:73-80
Two novel binuclear chiral anionic Zn(II) complexes, [Zn2LCl3]− (C2H5)3N+ 1 and [Zn2L(CH3COO)3]− (C2H5)3N+ 2 counterbalanced by triethyl ammonium cation, have been synthesized from ligand, 2,2′-((1E,1′E)-((1R,2R)-cyclohexane-1,2-diylbis(azany
Publikováno v:
Inorganic Chemistry Communications. 38:70-73
Two isostructural 3D coordination polymers (CPs) {[M(L 242 ) 2 ](ClO 4 ) 2 } n (MII = CdII for 1 and Zn II for 2 ) have been constructed from metal perchlorates and a tripyridyltriazole ligand 4-(4-pyridyl)-3,5-bis(2-pyridyl)-1,2,4-triazole (L 242 ).
Autor:
R. Szymczak, Rahman Bikas, Tadeusz Lis, Milosz Siczek, Hassan Hosseini-Monfared, Pavlo Aleshkevych
Publikováno v:
Inorganic Chemistry Communications. 35:172-175
The first mixed-metal azido bridged complex of Cr(III)–Na(I) has been prepared and its structure is determined. Reaction of chromium(III) chloride and sodium azide with bis-[(E)-N′-(1-(pyridin-2-yl)ethylidene)]carbohydrazide (HL) produced the tet
Autor:
Chee-Hun Kwak, Joo-Eun Jee
Publikováno v:
Inorganic Chemistry Communications. 33:95-98
A dimeric complex of [(tren)Ni(μ-Cl)2Ni(tren)](ClO4)2 (1) and a polymeric complex of {[Fe(CN)6][Ni(tren)]2[Ni(tren)(H2O)]2}Cl2(ClO4)2·4H2O (2), are isolated from the reaction of potassium ferricyanide, nickel chloride and tren and their X-ray struc
Publikováno v:
Inorganic Chemistry Communications. 26:72-76
N-(diethylthiocarbamoyl)benzimidoyl chloride reacts with o-aminoacetophenone 4-methylthiosemicarbazone under formation of a novel N2S2 benzamidine/thiosemicarbazone ligand (H2L). The reaction of H2L with [ReNCl2(PPh3)2] yields a red complex of the co