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Publikováno v:
Inorganic Chemistry. 55:7852-7858
A Re(I) carbonyl complex derived from 2-(2-pyridyl)-benzothiazole (pbt), [Re(H2O)(CO)3(pbt)](CF3SO3) (1), rapidly releases CO under low-power UV illumination. CO photorelease from 1 is accompanied by a change in luminescence from orange to deep blue.
Autor:
Pradip K. Mascharak, Jorge Jimenez, Annmarie Dominguez, W. M. Chamil Sameera, Jorge Martinez-Gonzalez, Indranil Chakraborty
Publikováno v:
Inorganic chemistry. 57(4)
A photoactive manganese carbonyl complex derived from dansylimidazole (Imdansyl), namely, [Mn(Imdansyl)(CO)3(phen)](CF3SO3) (1), has been synthesized and structurally characterized. This is the first luminescent manganese carbonyl-based photoCORM rep