Zobrazeno 1 - 10
of 16
pro vyhledávání: '"35"'
Autor:
Stefano Zacchini, Piero Zanello, Cristina Femoni, Cristina Tiozzo, Fabrizia Fabrizi de Biani, Dmitriy S. Dolzhnikov, Maria Carmela Iapalucci, Giuliano Longoni, Davide Collini
Publikováno v:
Inorganic Chemistry. 50:2790-2798
The previously ill-characterized [HxRh22(CO)35]4−/5− carbonyl cluster has been obtained as a byproduct of the synthesis of [H3Rh13(CO)24]2− and effectively separated by metathesis of their sodium salts with [NEt4]Cl. Although the yields are mod
Autor:
Brian M. Hoffman, Dennis G. H. Hetterscheid, R. Adam Kinney, Richard R. Schrock, Brian S. Hanna
Publikováno v:
Inorganic Chemistry. 49:704-713
MoN(2) (Mo = [(HIPTNCH(2)CH(2))(3)N]Mo, where HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)) is the first stage in the reduction of N(2) to NH(3) by Mo. Its reaction with dihydrogen in fluid solution yields "MoH(2)", a molybdenum-dihydrogen compound.
Autor:
Frank Neese, Eric L. Klein, Dmitry Ganyushin, Christoph Riplinger, John H. Enemark, Kayunta Johnson-Winters, Andrei V. Astashkin
Publikováno v:
Inorganic chemistry. 48(11)
Electron spin echo envelope modulation (ESEEM) investigations were carried out on samples of the low-pH (lpH) form of vertebrate sulfite oxidase (SO) prepared with (35)Cl- and (37)Cl-enriched buffers, as well as with buffer containing the natural abu
Autor:
James C. Howard, Debra Jones Jackson, Jamie Wilcox, Michael Cochran, Tibor Koritsanszky, Gary Wulfsberg
Publikováno v:
Inorganic chemistry. 43(6)
Ionic and covalent derivatives of the chlorine analogue of the nonbasic, weakly coordinating triflate ion, Cl3CSO3(-) or "trichlate" ion, have been prepared and compared with the corresponding more strongly coordinated chloroacetates, Cl(x)CH(3-x)CO(
Publikováno v:
Inorganic Chemistry. 57:5273-5281
We report the serendipitous discovery of an optical mercury sensor while trying to develop a water-soluble manganese probe. The sensor is based on a pentaaza macrocycle conjugated to a hemicyanine dye. The pentaaza macrocycle earlier designed in our
Autor:
Samia Benmansour, Josefina Perles, Félix Zamora, Carlos J. Gómez-García, Diego Hernández, Esther Delgado, Avelino Martín, Elisa Hernández
Publikováno v:
Inorganic chemistry. 54(5)
Coordination polymer chains have been formed by the direct reaction between HSC6H2Cl2SH and FeCl3·6H2O in the presence of an aqueous solution of the corresponding alkali-metal hydroxide (M = Li, Na, and K) or carbonate (M = Rb and Cs). The structure
Publikováno v:
Inorganic Chemistry. 45:2627-2634
The reaction of the asymmetric 3-aminomethylpyridine (3-amp) ligand with silver(I) tetrafluoroborate (AgBF4) produces an array of structural motifs that depend on the ratio of the reactants present and crystallization temperature. With a 1:1 ratio of
Autor:
Claudio Barberato, M. P. D. Mattioli, Antonio J. Costa-Filho, Rafael Calvo, Eduarde E. Castellano, Claudia Elisabeth Munte, Otaciro R. Nascimento
Publikováno v:
Inorganic Chemistry. 38:4413-4421
We report the synthesis and the structural and magnetic characterization of two new compounds: dibromobis(pdmp)copper(II), CuBr(2)C(22)H(24)N(4) (1), and dichlorobis(pdmp)copper(II), CuCl(2)C(22)H(24)N(4) (2), where pdmp = 1-phenyl-3,5-dimethylpyrazo
Publikováno v:
University of Copenhagen
The H+- and Cl--assisted dissociation kinetics and the stabilities of the complexes [Hg(sar)](2+) and [Hg((NH2)(2)-sar)](2+) (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane and (NH2)(2)-sar = 1,8-diamino-sar) were determined. The Hg2+ dissociatio
Autor:
Donald E. Linn, Sidney G. Gibbins
Publikováno v:
Inorganic Chemistry. 36:3461-3465
Solution spectroscopic and chemical behavior was examined in the case of the homoleptic hydridic anion of iron [FeH(6)](4)(-). Examination of the UV-visible spectrum in THF revealed a LMCT band which occurs at 41 x 10(3) cm(-)(1) (epsilon = 1200 L mo