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Publikováno v:
Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2015, 44 (32), pp.14403--14410. ⟨10.1039/C5DT01511A⟩
Dalton Transactions, 2015, 44 (32), pp.14403--14410. ⟨10.1039/C5DT01511A⟩
Dalton Transactions, Royal Society of Chemistry, 2015, 44 (32), pp.14403--14410. ⟨10.1039/C5DT01511A⟩
Dalton Transactions, 2015, 44 (32), pp.14403--14410. ⟨10.1039/C5DT01511A⟩
Reaction of [(?5-C5Me5)CoCl]2 with a two-fold excess of [LiBH4�thf] followed by heating with an excess of Se powder produces the dicobaltaselenaborane species [{(?5-C5Me5)Co}2B2H2Se2], 1, in good yield. The geometry of 1 resembles a nido pentagonal
Publikováno v:
IndraStra Global.
This work reports the results of a thermally driven cluster expansion of arachno-1-{?5-C5Me5IrH2}B 3H7, 1, with BH3�THF. In addition to the previously reported product, arachno-1-{?5-C5Me 5IrH}B4H9, 2, formed at lower temperatures, reaction at 100