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Publikováno v:
Dalton Trans.. 42:542-549
The formation of [Cm(SO(4))(n)](3-2n) complexes (n = 1, 2, 3) in an aquatic solution is studied by time resolved laser fluorescence spectroscopy as a function of the ligand concentration, the ionic strength (NaClO(4)) and the temperature (25 to 200
Autor:
Mark R. St J. Foreman, Thomas Fanghänel, Petra J. Panak, Andreas Geist, Sascha Trumm, Georg Lieser
Publikováno v:
Dalton Trans.. 39:923-929
The complexation of Cm(III) and Eu(III) with 4-t-butyl-6,6'-bis-(5,6-diethyl-1,2,4-triazin-3-yl)-2,2'-bipyridine (t-Bu-C2-BTBP) in water/2-propanol solution is studied. With increasing ligand concentration, 1 : 2 complexes [M(t-Bu-C2-BTBP)(2)(H(2)O)]