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Publikováno v:
Chemical Science. 7:2532-2536
A nitrogen-based analogue of the Schrock and Clark “yl-ene-yne” complex, W(CBut)(CHBut)(CH2But)(dmpe), has been prepared. The new complex is the nitrido, imido, amido anion [NCr(NPh)(NPri2)2]−, which was structurally characterized with the [K(c
Publikováno v:
Chemical Science
A complex with single, double and triple bonds between nitrogen and the same metal center has been synthesized, [NCr(NPh)(NPri 2)2]–. The complex shows differential activity, with some electrophiles attacking the imido and others the nitrido.