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Publikováno v:
Chem. Commun.. 53:11453-11456
Inspired by the zinc protoporphyrin found in red blood cells during heme production, we have developed a novel type of bimetallic Fe, Zn/N/C catalyst with high metal loading (Fe 1.2 wt% and Zn 1.7 wt%), demonstrating high activity and high stability
Autor:
Shudong Wang, Peyman Z. Moghadam, Xiaowei Liu, Tianjun Sun, Michael Fischer, Ya Guo, David Fairen-Jimenez, Andi Tao
Publikováno v:
Chem. Commun.. 53:11437-11440
In this work, we show a solvent-free “explosive” synthesis (SFES) method for the ultrafast and low-cost synthesis of metal-formate frameworks (MFFs). A combination of experiments and in-depth molecular modelling analysis – using grand canonical
Autor:
Lequan Liu, Toyokazu Tanabe, Shigenori Ueda, Gubbala V. Ramesh, Yoshiki Sakuma, Maidhily Manikandan, Jinhua Ye, Satoshi Koyasu, Rajesh Kodiyath, Masahiro Miyauchi, Takao Gunji, Tadaaki Nagao, Thang Duy Dao, Hideki Abe
Publikováno v:
Chem. Commun.. 50:15553-15556
Skeletal gold nanocages (Au NCs) are synthesized and coated with TiO2 layers (TiO2–Au NCs). The TiO2–Au NCs exhibit enhanced photodecomposition activity toward acetaldehyde under visible light (>400 nm) illumination because hot electrons are gene
Publikováno v:
Chem. Commun.. 50:13373-13376
Silver-enhanced fluorescence was coupled with a bio-barcode assay to facilitate a dual amplification assay to demonstrate a non-enzymatic approach for simple and sensitive detection of DNA. In the assay design, magnetic nanoparticles seeded with silv
Publikováno v:
Chem. Commun.. 50:13805-13808
A facile drug screening method based on synthesis of fluorescent gold nanoclusters inside albumin proteins loaded with small molecular drugs and comparing the relative fluorescence intensities of the resultant gold nanoclusters has been developed and
Autor:
Takao Ikariya, Shigeki Kuwata
Publikováno v:
Chem. Commun.. 50:14290-14300
Metal-ligand bifunctional cooperation has attracted much attention because it offers a powerful methodology to realize a number of highly efficient and selective catalysts. In this article, recent developments in the metal-ligand cooperative reaction
Publikováno v:
Chem. Commun.. 50:5633-5636
Supported Au nanoparticles showed efficient catalytic performance for the ring rearrangement of 5-hydroxymethylfurfural (HMF) to a cyclopentanone derivative, 3-hydroxymethylcyclopentanone (HCPN), by taking advantage of the selective hydrogenation on
Autor:
Yury Minko, Ilan Marek
Publikováno v:
Chem. Commun.. 50:12597-12611
Reactions that involve metal enolate species are amongst the most versatile carbon-carbon bond forming processes available to synthetic chemists. Enolate species are involved in a multitude of powerful applications in asymmetric organic synthesis, bu
Publikováno v:
Chem. Commun.. 50:14971-14974
Phytate, an abundant molecule in eukaryotic cells, interacts strongly with inorganic cations and polyamines. This interaction is essential for determining the possible functions of this biomolecule. We present here the first solution and crystallogra
Autor:
Satyaprasad P. Senanayak, K. S. Narayan, Snigdha Panda, Anjan Bedi, Ashish K. Asatkar, Sanjio S. Zade
Publikováno v:
Chem. Commun.. 50:7036-7039
A new thiophene-based salphen-type ligand, 1, and its Cu(II) and Zn(II) complexes, 1·Cu and 1·Zn·MeOH, were designed and synthesized. These metal organic complexes (MOCs), with ultra-close π-stacking interactions were explored as a novel class of