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Publikováno v:
The Journal of Physical Chemistry. 94:6987-6995
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net rate of formation of H{sub L} is reduced upon app
Publikováno v:
The Journal of Physical Chemistry. 92:3708-3711
For the series of chromophore-quencher complexes, ((4,4'-(X)/sub 2/-bpy)Re(CO)/sub 3/(MQ/sup +/))/sup 2 +/ (X = C(O)OEt, H, NH/sub 2/) in a 4:1 (v/v) EtOH/MeOH glass at 77 K, intramolecular-electron-transfer quenching via ((bpy/sup .-/)Re/sup II/(CO)