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pro vyhledávání: '"398"'
Publikováno v:
Inorganica Chimica Acta. 155:139-144
Equilibrium constants for the reaction [Fe(H 2 O) 6 ] 3+ +Cl − ⇌[Fe(H 2 O) 5 Cl] 2+ were determined as a function of temperature over the range 298 to 398 K. As predicted by temperature corrected Pourbaix pH-potential diagrams and subsequently sh
Publikováno v:
Inorganica Chimica Acta. 56:143-148
The kinetics of the reaction of low spin ferric haem undecapeptide (HUPIII) with H2O2 at pH 7.0 and 10.4 at 22 °C have been investigated by stopped flow spectroscopy at 398 nm and analysed by non-linear numerical integration and optimization techniq
Publikováno v:
Inorganica Chimica Acta. 362:4185-4190
A copper(I) complex [Cu(CETH)2Cl] (Ia), where CETH = cuminaldehyde-4-ethyl-3-thiosemicarbazone (I), is prepared and structurally characterised. The complex crystallizes in orthorhombic space group pna2(1) with the unit cell parameters; a = 9.8598(14)
Autor:
James K. Hurst, Yabin Lei
Publikováno v:
Inorganica Chimica Acta. 226:179-185
Electron paramagnetic resonance and Raman spectroscopies have been used to identify component species in acidic solutions containing the water oxidation catalyst (µ-oxo)bis[cis-aquabis(2,2'-bipyridine)ruthenium(III)] ([3,3]) and Ce^(4+) ions. One-el
Autor:
O. G. Éllert, Yu. V. Rakitin, V.T. Kalinnikov, B. Orazsakhatov, A. A. Pasynskii, Igor L. Eremenko, Vladimir M. Novotortsev
Publikováno v:
Inorganica Chimica Acta. 39:91-97
The complex (CpCrSCMe 3 ) 2 S (I), contains a CrCr bond (2.689 A) and at the same time shows antiferromagnetic properties (−2J = 430 cm −1 ). It reacts with PhEH (E is S, Se) or MeI to give binuclear complexes (CpCrEPh) 2 S or [(CpCrSCMe 3 ) 2
Publikováno v:
Inorganica Chimica Acta. 79:161-164
Substitution of certain divalent transition metal ions, i.e. Co(II), Ni(II), Cu(II) and Fe(II), for the active site ion of horse liver alcohol dehydrogenase yields catalytically active enzyme derivatives [1–4]. Since catalysis occurs via inner-sphe